Sample Originator: Simon J. Coles, Michael B. Hursthouse, M. B. Berry, L. Patient and J. D. Kilburn.



Identification Number:10.5258/ecrystals/85
Date Created:23 January 2001
Deposited On:21 Jan 2008 15:28
Deposited By:A.N. Admin

Depositor Comments

Silylated methylenecyclopropyl hydrazones on treatment with BF3·Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates. DOI: 10.1039/b306636c

Data collection parameters

Chemical formulaC18 H28 N2 O2 S Si
Crystal morphology
Crystal systemMonoclinic
Space group symbolP2(1)/c
Cell length a14.291(3)
Cell length b11.709(2)
Cell length c13.341(3)
Cell angle alpha90.00
Cell angle beta115.86(3)
Cell angle gamma90.00
Data collection temperature150(2)

Refinement results

Solution figure of merit0.0925
R Factor (Obs)0.0691
R Factor (All)0.1251
Weighted R Factor (Obs)0.1625
Weighted R Factor (All)0.1942

Citation: Coles, Simon J. and Hursthouse, Michael B. and Berry, M. B. and Patient, L. and Kilburn, J. D. (2001) University of Southampton, Crystal Structure Report Archive. (doi:10.5258/ecrystals/85)
Export as: oreChem EndNote BibTeX ASCII Citation

Repository Staff Only: item control page