Sample Originator: J. D. Kilburn, Michael B. Hursthouse, Simon J. Coles, M. B. Berry and L. Patient.



Identification Number:10.5258/ecrystals/88
Date Created:08 April 2002
Deposited On:21 Jan 2008 15:28
Deposited By:A.N. Admin

Depositor Comments

Silylated methylenecyclopropyl hydrazones on treatment with BF3·Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates. DOI: 10.1039/b306636c

Data collection parameters

Chemical formulaC18 H28 N2 O2 S Si
Crystal morphology
Crystal systemMonoclinic
Space group symbolP2(1)/c
Cell length a9.4824(2)
Cell length b22.6655(6)
Cell length c10.0368(3)
Cell angle alpha90.00
Cell angle beta116.1400(10)
Cell angle gamma90.00
Data collection temperature120(2)

Refinement results

Solution figure of merit0.0695
R Factor (Obs)0.0474
R Factor (All)0.0647
Weighted R Factor (Obs)0.1236
Weighted R Factor (All)0.1348

Citation: Kilburn, J. D. and Hursthouse, Michael B. and Coles, Simon J. and Berry, M. B. and Patient, L. (2002) University of Southampton, Crystal Structure Report Archive. (doi:10.5258/ecrystals/88)
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