data_s92
 
_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C39 H36 Cl5 N O4 P Rh'
_chemical_formula_weight          893.82
 
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Rh'  'Rh'  -1.1178   0.9187
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_symmetry_cell_setting            Monoclinic
_symmetry_space_group_name_H-M    P2(1)/c
 
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'
 
_cell_length_a                    21.480(4)
_cell_length_b                    7.2675(15)
_cell_length_c                    25.155(5)
_cell_angle_alpha                 90.00
_cell_angle_beta                  103.79(3)
_cell_angle_gamma                 90.00
_cell_volume                      3813.7(13)
_cell_formula_units_Z             4
_cell_measurement_temperature     150(2)
_cell_measurement_reflns_used     17658
_cell_measurement_theta_min       2.91
_cell_measurement_theta_max       30.51
 
_exptl_crystal_description        block
_exptl_crystal_colour             red
_exptl_crystal_size_max           0.15
_exptl_crystal_size_mid           0.15
_exptl_crystal_size_min           0.15
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.557
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              1816
_exptl_absorpt_coefficient_mu     0.882
_exptl_absorpt_correction_type    multi-scans
_exptl_absorpt_correction_T_min   0.8791
_exptl_absorpt_correction_T_max   0.8791
_exptl_absorpt_process_details    ?
 
_exptl_special_details
;
 ?
;
 
_diffrn_ambient_temperature       150(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'Nonius FR591 rotating anode'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   'Nonius KappaCCD Area Detector'
_diffrn_measurement_method        'Phi and Omega scans to fill Ewald Sphere'
_diffrn_detector_area_resol_mean  9.091
_diffrn_standards_number          ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         ?
_diffrn_reflns_number             30859
_diffrn_reflns_av_R_equivalents   0.0496
_diffrn_reflns_av_sigmaI/netI     0.0522
_diffrn_reflns_limit_h_min        -27
_diffrn_reflns_limit_h_max        26
_diffrn_reflns_limit_k_min        -9
_diffrn_reflns_limit_k_max        9
_diffrn_reflns_limit_l_min        -32
_diffrn_reflns_limit_l_max        32
_diffrn_reflns_theta_min          2.92
_diffrn_reflns_theta_max          27.50
_reflns_number_total              8591
_reflns_number_gt                 6856
_reflns_threshold_expression      >2sigma(I)
 
_computing_data_collection        ?
_computing_cell_refinement        'DENZO, COLLECT'
_computing_data_reduction         'DENZO, COLLECT'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics     'CAMERON (Watkin, Pearce 1995)'
_computing_publication_material   ?
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
 
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[σ²(Fo²)+(0.0575P)²+2.1256P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     mixed
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          8591
_refine_ls_number_parameters      470
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0573
_refine_ls_R_factor_gt            0.0400
_refine_ls_wR_factor_ref          0.1061
_refine_ls_wR_factor_gt           0.0964
_refine_ls_goodness_of_fit_ref    1.025
_refine_ls_restrained_S_all       1.025
_refine_ls_shift/su_max           0.029
_refine_ls_shift/su_mean          0.000
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Rh1 Rh 0.277895(10) 0.98367(3) 0.189238(8) 0.01604(8) Uani 1 1 d . . .
Cl1 Cl 0.20937(3) 0.73231(9) 0.15069(3) 0.02346(15) Uani 1 1 d . . .
Cl2 Cl 0.36936(3) 0.78781(9) 0.19382(3) 0.02184(15) Uani 1 1 d . . .
P1 P 0.26975(3) 0.90192(9) 0.27476(3) 0.01581(14) Uani 1 1 d . . .
O1 O 0.33336(8) 0.8362(2) 0.31948(7) 0.0181(4) Uani 1 1 d . . .
O2 O 0.24600(8) 1.0746(2) 0.30617(7) 0.0174(4) Uani 1 1 d . . .
O3 O 0.09312(10) 0.6995(3) 0.22500(8) 0.0353(5) Uani 1 1 d . . .
O4 O 0.02602(10) 0.7056(3) 0.28042(9) 0.0393(6) Uani 1 1 d . . .
N1 N 0.22071(10) 0.7300(3) 0.27676(9) 0.0186(5) Uani 1 1 d . . .
H1 H 0.2054 0.6733 0.2455 0.022 Uiso 1 1 calc R . .
C1 C 0.37850(12) 0.9741(3) 0.34016(11) 0.0179(5) Uani 1 1 d . . .
C2 C 0.43399(13) 0.9842(4) 0.31958(12) 0.0222(6) Uani 1 1 d . . .
H2 H 0.4418 0.8954 0.2943 0.027 Uiso 1 1 calc R . .
C3 C 0.47608(13) 1.1242(4) 0.33679(11) 0.0245(6) Uani 1 1 d . . .
H3 H 0.5140 1.1311 0.3238 0.029 Uiso 1 1 calc R . .
C4 C 0.46441(13) 1.2598(4) 0.37380(11) 0.0226(6) Uani 1 1 d . . .
C5 C 0.40927(13) 1.2429(4) 0.39580(11) 0.0202(5) Uani 1 1 d . . .
C6 C 0.36652(12) 1.0926(4) 0.37881(10) 0.0179(5) Uani 1 1 d . . .
C7 C 0.39747(13) 1.3852(4) 0.43096(11) 0.0246(6) Uani 1 1 d . . .
H7 H 0.3615 1.3764 0.4466 0.030 Uiso 1 1 calc R . .
C8 C 0.43687(16) 1.5335(4) 0.44253(14) 0.0326(7) Uani 1 1 d . . .
H8 H 0.4276 1.6281 0.4656 0.039 Uiso 1 1 calc R . .
C9 C 0.49106(16) 1.5487(5) 0.42084(14) 0.0370(8) Uani 1 1 d . . .
H9 H 0.5183 1.6530 0.4293 0.044 Uiso 1 1 calc R . .
C10 C 0.50465(14) 1.4146(4) 0.38779(13) 0.0313(7) Uani 1 1 d . . .
H10 H 0.5419 1.4251 0.3738 0.038 Uiso 1 1 calc R . .
C11 C 0.30736(13) 1.0670(4) 0.39909(11) 0.0184(5) Uani 1 1 d . . .
C12 C 0.24919(13) 1.0650(3) 0.36251(10) 0.0174(5) Uani 1 1 d . . .
C13 C 0.19066(13) 1.0550(4) 0.37835(11) 0.0212(6) Uani 1 1 d . . .
H13 H 0.1510 1.0650 0.3519 0.025 Uiso 1 1 calc R . .
C14 C 0.19193(14) 1.0306(4) 0.43248(12) 0.0239(6) Uani 1 1 d . . .
H14 H 0.1527 1.0263 0.4437 0.029 Uiso 1 1 calc R . .
C15 C 0.25048(14) 1.0116(3) 0.47214(12) 0.0208(6) Uani 1 1 d . . .
C16 C 0.30952(13) 1.0331(3) 0.45566(11) 0.0190(5) Uani 1 1 d . . .
C17 C 0.36777(14) 1.0054(4) 0.49518(12) 0.0223(6) Uani 1 1 d . . .
H17 H 0.4073 1.0197 0.4850 0.027 Uiso 1 1 calc R . .
C18 C 0.36803(15) 0.9584(4) 0.54771(12) 0.0266(6) Uani 1 1 d . . .
H18 H 0.4077 0.9392 0.5735 0.032 Uiso 1 1 calc R . .
C19 C 0.30998(15) 0.9380(4) 0.56419(11) 0.0270(6) Uani 1 1 d . . .
H19 H 0.3105 0.9051 0.6008 0.032 Uiso 1 1 calc R . .
C20 C 0.25333(15) 0.9658(4) 0.52725(12) 0.0252(6) Uani 1 1 d . . .
H20 H 0.2145 0.9542 0.5388 0.030 Uiso 1 1 calc R . .
C21 C 0.19978(13) 0.6607(4) 0.32248(11) 0.0204(6) Uani 1 1 d . . .
C22 C 0.24448(14) 0.6112(4) 0.36991(11) 0.0246(6) Uani 1 1 d . . .
H22 H 0.2889 0.6175 0.3709 0.029 Uiso 1 1 calc R . .
C23 C 0.22499(16) 0.5527(4) 0.41560(13) 0.0312(7) Uani 1 1 d . . .
H23 H 0.2561 0.5212 0.4480 0.037 Uiso 1 1 calc R . .
C24 C 0.16049(17) 0.5399(5) 0.41452(14) 0.0361(8) Uani 1 1 d . . .
H24 H 0.1473 0.5008 0.4462 0.043 Uiso 1 1 calc R . .
C25 C 0.11578(15) 0.5837(4) 0.36774(13) 0.0315(7) Uani 1 1 d . . .
H25 H 0.0715 0.5741 0.3672 0.038 Uiso 1 1 calc R . .
C26 C 0.13401(13) 0.6426(4) 0.32050(11) 0.0233(6) Uani 1 1 d . . .
C27 C 0.08477(14) 0.6862(4) 0.27062(12) 0.0265(6) Uani 1 1 d . . .
C28 C -0.02554(16) 0.7299(6) 0.23258(16) 0.0502(10) Uani 1 1 d . . .
H28A H -0.0154 0.8322 0.2107 0.075 Uiso 1 1 calc R . .
H28B H -0.0652 0.7572 0.2438 0.075 Uiso 1 1 calc R . .
H28C H -0.0311 0.6169 0.2107 0.075 Uiso 1 1 calc R . .
C29 C 0.32992(13) 1.2211(4) 0.16814(11) 0.0212(6) Uani 1 1 d . . .
C30 C 0.29068(13) 1.2790(3) 0.20381(11) 0.0217(6) Uani 1 1 d . . .
C31 C 0.22464(14) 1.2382(4) 0.17649(12) 0.0233(6) Uani 1 1 d . . .
C32 C 0.22445(14) 1.1643(4) 0.12385(12) 0.0246(6) Uani 1 1 d . . .
C33 C 0.28907(14) 1.1471(4) 0.11892(11) 0.0231(6) Uani 1 1 d . . .
C34 C 0.40072(14) 1.2487(4) 0.17954(13) 0.0276(6) Uani 1 1 d . . .
H34A H 0.4218 1.1729 0.2109 0.041 Uiso 1 1 calc R . .
H34B H 0.4108 1.3786 0.1879 0.041 Uiso 1 1 calc R . .
H34C H 0.4161 1.2127 0.1473 0.041 Uiso 1 1 calc R . .
C35 C 0.31527(15) 1.3801(4) 0.25591(12) 0.0259(6) Uani 1 1 d . . .
H35A H 0.3553 1.3231 0.2762 0.039 Uiso 1 1 calc R . .
H35B H 0.2834 1.3752 0.2780 0.039 Uiso 1 1 calc R . .
H35C H 0.3234 1.5086 0.2479 0.039 Uiso 1 1 calc R . .
C36 C 0.16706(14) 1.2878(4) 0.19693(13) 0.0305(7) Uani 1 1 d . . .
H36A H 0.1513 1.4090 0.1827 0.046 Uiso 1 1 calc R . .
H36B H 0.1786 1.2912 0.2370 0.046 Uiso 1 1 calc R . .
H36C H 0.1334 1.1957 0.1845 0.046 Uiso 1 1 calc R . .
C37 C 0.16659(17) 1.1143(5) 0.08053(13) 0.0401(8) Uani 1 1 d . . .
H37A H 0.1300 1.0979 0.0970 0.060 Uiso 1 1 calc R . .
H37B H 0.1746 0.9994 0.0629 0.060 Uiso 1 1 calc R . .
H37C H 0.1571 1.2127 0.0532 0.060 Uiso 1 1 calc R . .
C38 C 0.30997(17) 1.0733(4) 0.07053(12) 0.0327(7) Uani 1 1 d . . .
H38A H 0.3122 1.1741 0.0452 0.049 Uiso 1 1 calc R . .
H38B H 0.2791 0.9811 0.0519 0.049 Uiso 1 1 calc R . .
H38C H 0.3523 1.0164 0.0827 0.049 Uiso 1 1 calc R . .
C01 C 0.04641(19) 0.6485(6) 0.09149(17) 0.0547(11) Uani 1 1 d . . .
H01 H 0.0837(18) 0.670(5) 0.1242(15) 0.043(10) Uiso 1 1 d . . .
Cl01 Cl 0.00420(7) 0.4639(2) 0.11001(6) 0.0888(4) Uani 1 1 d . . .
Cl02 Cl -0.00232(8) 0.8405(2) 0.07554(7) 0.1055(5) Uani 1 1 d . . .
Cl03 Cl 0.07793(5) 0.5918(2) 0.03588(5) 0.0871(5) Uani 1 1 d . . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Rh1 C31 2.158(3) . ?
Rh1 C30 2.184(3) . ?
Rh1 C29 2.189(3) . ?
Rh1 C33 2.191(3) . ?
Rh1 C32 2.202(3) . ?
Rh1 P1 2.2782(8) . ?
Rh1 Cl1 2.4008(8) . ?
Rh1 Cl2 2.4065(7) . ?
P1 O1 1.621(2) . ?
P1 O2 1.6285(18) . ?
P1 N1 1.643(2) . ?
O1 C1 1.405(3) . ?
O2 C12 1.404(3) . ?
O3 C27 1.207(3) . ?
O4 C27 1.350(3) . ?
O4 C28 1.439(4) . ?
N1 C21 1.423(3) . ?
C1 C6 1.368(4) . ?
C1 C2 1.410(4) . ?
C2 C3 1.361(4) . ?
C3 C4 1.418(4) . ?
C4 C10 1.411(4) . ?
C4 C5 1.427(4) . ?
C5 C7 1.422(4) . ?
C5 C6 1.425(4) . ?
C6 C11 1.490(3) . ?
C7 C8 1.358(4) . ?
C8 C9 1.403(5) . ?
C9 C10 1.357(5) . ?
C11 C12 1.364(4) . ?
C11 C16 1.434(4) . ?
C12 C13 1.408(3) . ?
C13 C14 1.367(4) . ?
C14 C15 1.413(4) . ?
C15 C20 1.413(4) . ?
C15 C16 1.434(4) . ?
C16 C17 1.415(4) . ?
C17 C18 1.364(4) . ?
C18 C19 1.412(4) . ?
C19 C20 1.359(4) . ?
C21 C22 1.389(4) . ?
C21 C26 1.408(4) . ?
C22 C23 1.380(4) . ?
C23 C24 1.383(5) . ?
C24 C25 1.367(5) . ?
C25 C26 1.404(4) . ?
C26 C27 1.470(4) . ?
C29 C30 1.433(4) . ?
C29 C33 1.440(4) . ?
C29 C34 1.492(4) . ?
C30 C31 1.452(4) . ?
C30 C35 1.485(4) . ?
C31 C32 1.428(4) . ?
C31 C36 1.492(4) . ?
C32 C33 1.428(4) . ?
C32 C37 1.490(4) . ?
C33 C38 1.494(4) . ?
C01 Cl02 1.733(4) . ?
C01 Cl03 1.742(4) . ?
C01 Cl01 1.744(5) . ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
C31 Rh1 C30 39.06(11) . . ?
C31 Rh1 C29 64.63(10) . . ?
C30 Rh1 C29 38.26(9) . . ?
C31 Rh1 C33 64.63(10) . . ?
C30 Rh1 C33 64.47(10) . . ?
C29 Rh1 C33 38.40(11) . . ?
C31 Rh1 C32 38.22(11) . . ?
C30 Rh1 C32 64.00(11) . . ?
C29 Rh1 C32 63.52(11) . . ?
C33 Rh1 C32 37.95(10) . . ?
C31 Rh1 P1 101.92(8) . . ?
C30 Rh1 P1 97.62(7) . . ?
C29 Rh1 P1 126.37(8) . . ?
C33 Rh1 P1 162.10(8) . . ?
C32 Rh1 P1 135.83(7) . . ?
C31 Rh1 Cl1 109.87(8) . . ?
C30 Rh1 Cl1 148.89(8) . . ?
C29 Rh1 Cl1 143.25(8) . . ?
C33 Rh1 Cl1 105.13(8) . . ?
C32 Rh1 Cl1 89.52(8) . . ?
P1 Rh1 Cl1 90.30(3) . . ?
C31 Rh1 Cl2 155.75(7) . . ?
C30 Rh1 Cl2 120.31(8) . . ?
C29 Rh1 Cl2 91.13(7) . . ?
C33 Rh1 Cl2 96.55(8) . . ?
C32 Rh1 Cl2 131.52(8) . . ?
P1 Rh1 Cl2 92.64(3) . . ?
Cl1 Rh1 Cl2 89.10(3) . . ?
O1 P1 O2 101.54(10) . . ?
O1 P1 N1 101.26(11) . . ?
O2 P1 N1 107.09(10) . . ?
O1 P1 Rh1 119.37(7) . . ?
O2 P1 Rh1 111.14(7) . . ?
N1 P1 Rh1 114.92(8) . . ?
C1 O1 P1 116.11(16) . . ?
C12 O2 P1 120.38(16) . . ?
C27 O4 C28 115.3(2) . . ?
C21 N1 P1 128.49(19) . . ?
C6 C1 O1 118.8(2) . . ?
C6 C1 C2 123.1(2) . . ?
O1 C1 C2 118.1(2) . . ?
C3 C2 C1 118.5(2) . . ?
C2 C3 C4 121.3(2) . . ?
C10 C4 C3 121.6(2) . . ?
C10 C4 C5 119.2(3) . . ?
C3 C4 C5 119.2(2) . . ?
C7 C5 C6 123.1(2) . . ?
C7 C5 C4 117.8(2) . . ?
C6 C5 C4 119.0(2) . . ?
C1 C6 C5 118.6(2) . . ?
C1 C6 C11 119.0(2) . . ?
C5 C6 C11 122.3(2) . . ?
C8 C7 C5 121.1(3) . . ?
C7 C8 C9 120.8(3) . . ?
C10 C9 C8 120.1(3) . . ?
C9 C10 C4 121.1(3) . . ?
C12 C11 C16 118.4(2) . . ?
C12 C11 C6 119.3(2) . . ?
C16 C11 C6 122.2(2) . . ?
C11 C12 O2 119.8(2) . . ?
C11 C12 C13 123.1(2) . . ?
O2 C12 C13 117.1(2) . . ?
C14 C13 C12 118.8(3) . . ?
C13 C14 C15 121.3(3) . . ?
C20 C15 C14 122.6(3) . . ?
C20 C15 C16 118.4(3) . . ?
C14 C15 C16 119.0(2) . . ?
C17 C16 C15 118.5(2) . . ?
C17 C16 C11 122.4(2) . . ?
C15 C16 C11 118.9(3) . . ?
C18 C17 C16 121.0(3) . . ?
C17 C18 C19 120.7(3) . . ?
C20 C19 C18 119.5(3) . . ?
C19 C20 C15 121.9(3) . . ?
C22 C21 C26 119.3(2) . . ?
C22 C21 N1 119.9(2) . . ?
C26 C21 N1 120.8(2) . . ?
C23 C22 C21 120.7(3) . . ?
C22 C23 C24 120.4(3) . . ?
C25 C24 C23 119.7(3) . . ?
C24 C25 C26 121.3(3) . . ?
C25 C26 C21 118.6(3) . . ?
C25 C26 C27 119.9(3) . . ?
C21 C26 C27 121.5(2) . . ?
O3 C27 O4 121.5(3) . . ?
O3 C27 C26 126.1(3) . . ?
O4 C27 C26 112.4(2) . . ?
C30 C29 C33 108.6(2) . . ?
C30 C29 C34 124.4(3) . . ?
C33 C29 C34 126.8(2) . . ?
C30 C29 Rh1 70.68(14) . . ?
C33 C29 Rh1 70.89(15) . . ?
C34 C29 Rh1 127.97(19) . . ?
C29 C30 C31 107.3(2) . . ?
C29 C30 C35 124.0(3) . . ?
C31 C30 C35 128.3(2) . . ?
C29 C30 Rh1 71.06(15) . . ?
C31 C30 Rh1 69.53(15) . . ?
C35 C30 Rh1 129.7(2) . . ?
C32 C31 C30 107.6(2) . . ?
C32 C31 C36 126.2(3) . . ?
C30 C31 C36 125.8(3) . . ?
C32 C31 Rh1 72.53(15) . . ?
C30 C31 Rh1 71.40(15) . . ?
C36 C31 Rh1 127.53(19) . . ?
C31 C32 C33 109.0(3) . . ?
C31 C32 C37 126.0(3) . . ?
C33 C32 C37 125.0(3) . . ?
C31 C32 Rh1 69.25(15) . . ?
C33 C32 Rh1 70.62(15) . . ?
C37 C32 Rh1 126.6(2) . . ?
C32 C33 C29 107.3(2) . . ?
C32 C33 C38 126.1(3) . . ?
C29 C33 C38 126.5(3) . . ?
C32 C33 Rh1 71.44(15) . . ?
C29 C33 Rh1 70.71(14) . . ?
C38 C33 Rh1 125.13(19) . . ?
Cl02 C01 Cl03 109.5(3) . . ?
Cl02 C01 Cl01 110.9(2) . . ?
Cl03 C01 Cl01 111.0(2) . . ?
 
_diffrn_measured_fraction_theta_max    0.980
_diffrn_reflns_theta_full              27.50
_diffrn_measured_fraction_theta_full   0.980
_refine_diff_density_max    0.601
_refine_diff_density_min   -1.031
_refine_diff_density_rms    0.101
