Sample Originator: Mark E. Light, J. L. Jimenez, Michael B. Hursthouse, J. C. Palacios, R. Gordillo, F. R. Clemente, P. Cintas, R. Babiano and M. Avalos.



Identification Number:10.5258/ecrystals/131
Date Created:20 April 2001
Deposited On:21 Jan 2008 15:29
Deposited By:A.N. Admin

Depositor Comments

This manuscript describes a one-pot, selective synthesis of optically active thiiranes by [3+2] cycloaddition of mesoionic dipoles with sugar aldehydes. Overall, the result is the formation of monosaccharide mimetics that display numerous functional groups for molecular recognition.

Data collection parameters

Chemical formulaC36 H38 N2 O10 S
Crystal morphology
Crystal systemMonoclinic
Space group symbolP2(1)
Cell length a7.8231(2)
Cell length b12.9445(3)
Cell length c17.3686(4)
Cell angle alpha90.00
Cell angle beta95.6680(10)
Cell angle gamma90.00
Data collection temperature180(2)

Refinement results

Solution figure of merit0.0947
R Factor (Obs)0.0418
R Factor (All)0.0475
Weighted R Factor (Obs)0.1006
Weighted R Factor (All)0.1037

Citation: Light, Mark E. and Jimenez, J. L. and Hursthouse, Michael B. and Palacios, J. C. and Gordillo, R. and Clemente, F. R. and Cintas, P. and Babiano, R. and Avalos, M. (2001) University of Southampton, Crystal Structure Report Archive. (doi:10.5258/ecrystals/131)
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