data_2010src0043

#Dr. S. L. James 

_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C40 H34 Cl2 P2 Pt'
_chemical_formula_weight          842.60
 
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt'  'Pt'  -1.7033   8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_symmetry_cell_setting            triclinic
_symmetry_space_group_name_H-M    P-1
 
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, -y, -z'
 
_cell_length_a                    10.0905(2)
_cell_length_b                    12.7583(4)
_cell_length_c                    14.4492(5)
_cell_angle_alpha                 100.026(2)
_cell_angle_beta                  98.124(2)
_cell_angle_gamma                 108.201(2)
_cell_volume                      1701.60(9)
_cell_formula_units_Z             2
_cell_measurement_temperature     120(2)
_cell_measurement_reflns_used     7424
_cell_measurement_theta_min       2.910
_cell_measurement_theta_max       27.485
 
_exptl_crystal_description        'Cut Blade'
_exptl_crystal_colour             colourless
_exptl_crystal_size_max           0.08
_exptl_crystal_size_mid           0.05
_exptl_crystal_size_min           0.02
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.645
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              832
_exptl_absorpt_coefficient_mu     4.403
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_correction_T_min   0.7196
_exptl_absorpt_correction_T_max   0.9171
_exptl_absorpt_process_details       'SADABS 2007/2 (Sheldrick, G.M., 2007)'

_exptl_special_details
;
SADABS was used to perform the Absorption correction
Parameter refinement on 27276 reflections reduced R(int) from 0.1425 to 0.0770
Ratio of minimum to maximum apparent transmission: 0.759411
The given Tmin and Tmax were generated using the SHELX SIZE command
;


_diffrn_ambient_temperature           120(2)
_diffrn_radiation_wavelength           0.71073
_diffrn_radiation_type                      MoK\a
_diffrn_radiation_source                  'Bruker-Nonius FR591 rotating anode'
_diffrn_radiation_monochromator    '10cm confocal mirrors'
_diffrn_measurement_device_type   
'Bruker-Nonius APEX II CCD camera on κ-goniostat'
_diffrn_measurement_method          'φ & ω scans'
_diffrn_detector_area_resol_mean   '4096x4096pixels / 62x62mm'
_diffrn_standards_number          ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         ?
_diffrn_reflns_number             28968
_diffrn_reflns_av_R_equivalents   0.0731
_diffrn_reflns_av_sigmaI/netI     0.0634
_diffrn_reflns_limit_h_min        -12
_diffrn_reflns_limit_h_max        13
_diffrn_reflns_limit_k_min        -16
_diffrn_reflns_limit_k_max        16
_diffrn_reflns_limit_l_min        -18
_diffrn_reflns_limit_l_max        18
_diffrn_reflns_theta_min          2.93
_diffrn_reflns_theta_max          27.48
_reflns_number_total              7716
_reflns_number_gt                 6475
_reflns_threshold_expression      >2sigma(I)
 
_computing_data_collection        
'COLLECT (Hooft, R.W.W., 1998)'
_computing_cell_refinement        
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
#Although determined using DirAx, the cell is refined in the HKL
#package during data reduction
_computing_data_reduction         
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)' 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 2008)' 
_computing_molecular_graphics     'ORTEP3 for Windows (Farrugia, 1997)'
_computing_publication_material   'WinGX (Farrugia, 1999)'
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
 
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[σ²(Fo²)+(0.0362P)²+18.5629P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          7716
_refine_ls_number_parameters      406
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0789
_refine_ls_R_factor_gt            0.0585
_refine_ls_wR_factor_ref          0.1378
_refine_ls_wR_factor_gt           0.1256
_refine_ls_goodness_of_fit_ref    1.118
_refine_ls_restrained_S_all       1.118
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Cl1 Cl 0.5815(2) 0.46105(17) 0.67390(14) 0.0331(4) Uani 1 1 d . . .
Cl2 Cl 0.7519(2) 0.65740(17) 0.86738(14) 0.0318(4) Uani 1 1 d . . .
Pt1 Pt 0.52305(3) 0.60097(3) 0.76875(2) 0.02509(10) Uani 1 1 d . . .
C1 C 0.2763(8) 0.6301(7) 0.6035(5) 0.0280(16) Uani 1 1 d . . .
C2 C 0.3943(8) 0.6784(7) 0.5622(6) 0.0325(18) Uani 1 1 d . . .
H2 H 0.4782 0.6602 0.5762 0.039 Uiso 1 1 calc R . .
C3 C 0.3894(10) 0.7495(7) 0.5037(6) 0.0368(19) Uani 1 1 d . . .
H3 H 0.4702 0.7808 0.4775 0.044 Uiso 1 1 calc R . .
C4 C 0.2667(10) 0.7779(7) 0.4807(6) 0.0349(18) Uani 1 1 d . . .
C5 C 0.1522(9) 0.7314(8) 0.5209(6) 0.037(2) Uani 1 1 d . . .
H5 H 0.0686 0.7500 0.5069 0.044 Uiso 1 1 calc R . .
C6 C 0.1558(9) 0.6575(7) 0.5815(6) 0.0333(18) Uani 1 1 d . . .
H6 H 0.0749 0.6262 0.6075 0.040 Uiso 1 1 calc R . .
C7 C 0.2591(12) 0.8564(9) 0.4183(8) 0.050(2) Uani 1 1 d . . .
H7 H 0.1681 0.8613 0.3976 0.060 Uiso 1 1 calc R . .
C8 C 0.3669(13) 0.9206(10) 0.3885(9) 0.064(3) Uani 1 1 d . . .
H8A H 0.4601 0.9187 0.4073 0.076 Uiso 1 1 calc R . .
H8B H 0.3515 0.9689 0.3481 0.076 Uiso 1 1 calc R . .
C9 C 0.2561(9) 0.3981(7) 0.5888(6) 0.0321(18) Uani 1 1 d . . .
C10 C 0.2486(9) 0.3912(8) 0.4914(6) 0.0347(19) Uani 1 1 d . . .
H10 H 0.2658 0.4580 0.4676 0.042 Uiso 1 1 calc R . .
C11 C 0.2161(9) 0.2867(8) 0.4286(7) 0.040(2) Uani 1 1 d . . .
H11 H 0.2080 0.2820 0.3616 0.048 Uiso 1 1 calc R . .
C12 C 0.1956(10) 0.1906(8) 0.4629(7) 0.045(2) Uani 1 1 d . . .
H12 H 0.1755 0.1197 0.4195 0.054 Uiso 1 1 calc R . .
C13 C 0.2040(11) 0.1956(8) 0.5596(8) 0.048(2) Uani 1 1 d . . .
H13 H 0.1886 0.1284 0.5827 0.057 Uiso 1 1 calc R . .
C14 C 0.2349(10) 0.2996(8) 0.6235(6) 0.041(2) Uani 1 1 d . . .
H14 H 0.2416 0.3036 0.6904 0.049 Uiso 1 1 calc R . .
C15 C 0.1656(8) 0.4948(7) 0.7473(6) 0.0297(17) Uani 1 1 d . . .
C16 C 0.0203(9) 0.4640(7) 0.7088(7) 0.0369(19) Uani 1 1 d . . .
H16 H -0.0108 0.4659 0.6441 0.044 Uiso 1 1 calc R . .
C17 C -0.0793(9) 0.4303(8) 0.7652(7) 0.043(2) Uani 1 1 d . . .
H17 H -0.1781 0.4100 0.7390 0.052 Uiso 1 1 calc R . .
C18 C -0.0347(10) 0.4262(8) 0.8593(7) 0.043(2) Uani 1 1 d . . .
H18 H -0.1030 0.4052 0.8978 0.051 Uiso 1 1 calc R . .
C19 C 0.1080(10) 0.4525(7) 0.8973(7) 0.039(2) Uani 1 1 d . . .
H19 H 0.1382 0.4477 0.9613 0.046 Uiso 1 1 calc R . .
C20 C 0.2069(9) 0.4861(7) 0.8410(6) 0.0313(17) Uani 1 1 d . . .
H20 H 0.3052 0.5037 0.8670 0.038 Uiso 1 1 calc R . .
P1 P 0.3014(2) 0.53287(17) 0.67689(14) 0.0261(4) Uani 1 1 d . . .
C21 C 0.6584(8) 0.8758(6) 0.8719(6) 0.0281(16) Uani 1 1 d . . .
C22 C 0.7113(9) 0.8931(7) 0.7883(6) 0.0334(18) Uani 1 1 d . . .
H22 H 0.6625 0.8421 0.7282 0.040 Uiso 1 1 calc R . .
C23 C 0.8321(9) 0.9827(7) 0.7929(6) 0.0331(18) Uani 1 1 d . . .
H23 H 0.8634 0.9952 0.7355 0.040 Uiso 1 1 calc R . .
C24 C 0.9098(8) 1.0558(7) 0.8810(6) 0.0322(18) Uani 1 1 d . . .
C25 C 0.8575(9) 1.0383(7) 0.9634(6) 0.0316(18) Uani 1 1 d . . .
H25 H 0.9086 1.0874 1.0239 0.038 Uiso 1 1 calc R . .
C26 C 0.7317(8) 0.9501(7) 0.9587(6) 0.0297(17) Uani 1 1 d . . .
H26 H 0.6961 0.9411 1.0154 0.036 Uiso 1 1 calc R . .
C27 C 1.0453(10) 1.1477(7) 0.8886(7) 0.042(2) Uani 1 1 d . . .
H27 H 1.0871 1.1976 0.9501 0.051 Uiso 1 1 calc R . .
C28 C 1.1141(12) 1.1678(9) 0.8204(8) 0.058(3) Uani 1 1 d . . .
H28A H 1.0771 1.1205 0.7575 0.070 Uiso 1 1 calc R . .
H28B H 1.2012 1.2299 0.8334 0.070 Uiso 1 1 calc R . .
C29 C 0.3520(8) 0.8033(7) 0.8163(6) 0.0285(17) Uani 1 1 d . . .
C30 C 0.3763(9) 0.8896(7) 0.7672(6) 0.0350(19) Uani 1 1 d . . .
H30 H 0.4686 0.9232 0.7554 0.042 Uiso 1 1 calc R . .
C31 C 0.2675(11) 0.9268(8) 0.7356(7) 0.047(2) Uani 1 1 d . . .
H31 H 0.2854 0.9853 0.7015 0.057 Uiso 1 1 calc R . .
C32 C 0.1333(10) 0.8802(8) 0.7529(7) 0.044(2) Uani 1 1 d . . .
H32 H 0.0596 0.9077 0.7321 0.053 Uiso 1 1 calc R . .
C33 C 0.1062(9) 0.7937(8) 0.8003(6) 0.038(2) Uani 1 1 d . . .
H33 H 0.0129 0.7595 0.8105 0.046 Uiso 1 1 calc R . .
C34 C 0.2164(9) 0.7563(7) 0.8335(6) 0.0330(18) Uani 1 1 d . . .
H34 H 0.1984 0.6982 0.8681 0.040 Uiso 1 1 calc R . .
C35 C 0.4763(8) 0.7458(7) 0.9816(5) 0.0275(16) Uani 1 1 d . . .
C36 C 0.4268(10) 0.8215(7) 1.0350(6) 0.0372(19) Uani 1 1 d . . .
H36 H 0.4061 0.8792 1.0087 0.045 Uiso 1 1 calc R . .
C37 C 0.4077(9) 0.8124(8) 1.1272(6) 0.038(2) Uani 1 1 d . . .
H37 H 0.3722 0.8634 1.1632 0.045 Uiso 1 1 calc R . .
C38 C 0.4393(10) 0.7312(9) 1.1664(7) 0.043(2) Uani 1 1 d . . .
H38 H 0.4267 0.7266 1.2297 0.052 Uiso 1 1 calc R . .
C39 C 0.4900(9) 0.6549(7) 1.1144(6) 0.0363(19) Uani 1 1 d . . .
H39 H 0.5110 0.5979 1.1417 0.044 Uiso 1 1 calc R . .
C40 C 0.5096(8) 0.6629(7) 1.0217(6) 0.0301(17) Uani 1 1 d . . .
H40 H 0.5456 0.6120 0.9861 0.036 Uiso 1 1 calc R . .
P2 P 0.4967(2) 0.75391(17) 0.85948(14) 0.0257(4) Uani 1 1 d . . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Cl1 Pt1 2.3338(19) . ?
Cl2 Pt1 2.3567(18) . ?
Pt1 P1 2.2506(19) . ?
Pt1 P2 2.2644(19) . ?
C1 C6 1.378(11) . ?
C1 C2 1.421(12) . ?
C1 P1 1.819(8) . ?
C2 C3 1.351(12) . ?
C2 H2 0.9500 . ?
C3 C4 1.408(12) . ?
C3 H3 0.9500 . ?
C4 C5 1.380(13) . ?
C4 C7 1.471(13) . ?
C5 C6 1.398(13) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.319(16) . ?
C7 H7 0.9500 . ?
C8 H8A 0.9500 . ?
C8 H8B 0.9500 . ?
C9 C10 1.383(12) . ?
C9 C14 1.399(13) . ?
C9 P1 1.836(8) . ?
C10 C11 1.389(12) . ?
C10 H10 0.9500 . ?
C11 C12 1.370(14) . ?
C11 H11 0.9500 . ?
C12 C13 1.377(14) . ?
C12 H12 0.9500 . ?
C13 C14 1.394(12) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 C20 1.393(12) . ?
C15 C16 1.396(11) . ?
C15 P1 1.815(9) . ?
C16 C17 1.393(13) . ?
C16 H16 0.9500 . ?
C17 C18 1.385(14) . ?
C17 H17 0.9500 . ?
C18 C19 1.377(13) . ?
C18 H18 0.9500 . ?
C19 C20 1.388(12) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C26 1.381(11) . ?
C21 C22 1.412(12) . ?
C21 P2 1.829(8) . ?
C22 C23 1.370(12) . ?
C22 H22 0.9500 . ?
C23 C24 1.398(12) . ?
C23 H23 0.9500 . ?
C24 C25 1.394(12) . ?
C24 C27 1.472(12) . ?
C25 C26 1.392(12) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 C28 1.300(14) . ?
C27 H27 0.9500 . ?
C28 H28A 0.9500 . ?
C28 H28B 0.9500 . ?
C29 C30 1.388(12) . ?
C29 C34 1.389(12) . ?
C29 P2 1.837(8) . ?
C30 C31 1.378(12) . ?
C30 H30 0.9500 . ?
C31 C32 1.376(14) . ?
C31 H31 0.9500 . ?
C32 C33 1.376(14) . ?
C32 H32 0.9500 . ?
C33 C34 1.398(12) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C35 C36 1.388(11) . ?
C35 C40 1.395(11) . ?
C35 P2 1.823(8) . ?
C36 C37 1.393(12) . ?
C36 H36 0.9500 . ?
C37 C38 1.362(14) . ?
C37 H37 0.9500 . ?
C38 C39 1.392(13) . ?
C38 H38 0.9500 . ?
C39 C40 1.398(12) . ?
C39 H39 0.9500 . ?
C40 H40 0.9500 . ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
P1 Pt1 P2 96.05(7) . . ?
P1 Pt1 Cl1 89.76(7) . . ?
P2 Pt1 Cl1 171.85(8) . . ?
P1 Pt1 Cl2 175.32(8) . . ?
P2 Pt1 Cl2 86.88(7) . . ?
Cl1 Pt1 Cl2 87.70(7) . . ?
C6 C1 C2 117.9(8) . . ?
C6 C1 P1 127.3(7) . . ?
C2 C1 P1 114.7(6) . . ?
C3 C2 C1 121.4(8) . . ?
C3 C2 H2 119.3 . . ?
C1 C2 H2 119.3 . . ?
C2 C3 C4 121.1(8) . . ?
C2 C3 H3 119.5 . . ?
C4 C3 H3 119.5 . . ?
C5 C4 C3 117.6(8) . . ?
C5 C4 C7 120.1(8) . . ?
C3 C4 C7 122.3(9) . . ?
C4 C5 C6 121.9(8) . . ?
C4 C5 H5 119.1 . . ?
C6 C5 H5 119.1 . . ?
C1 C6 C5 120.1(8) . . ?
C1 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C8 C7 C4 126.1(10) . . ?
C8 C7 H7 116.9 . . ?
C4 C7 H7 116.9 . . ?
C7 C8 H8A 120.0 . . ?
C7 C8 H8B 120.0 . . ?
H8A C8 H8B 120.0 . . ?
C10 C9 C14 119.5(7) . . ?
C10 C9 P1 122.8(7) . . ?
C14 C9 P1 117.6(6) . . ?
C9 C10 C11 120.1(9) . . ?
C9 C10 H10 120.0 . . ?
C11 C10 H10 120.0 . . ?
C12 C11 C10 120.3(9) . . ?
C12 C11 H11 119.9 . . ?
C10 C11 H11 119.9 . . ?
C11 C12 C13 120.6(8) . . ?
C11 C12 H12 119.7 . . ?
C13 C12 H12 119.7 . . ?
C12 C13 C14 119.9(10) . . ?
C12 C13 H13 120.1 . . ?
C14 C13 H13 120.1 . . ?
C13 C14 C9 119.7(9) . . ?
C13 C14 H14 120.2 . . ?
C9 C14 H14 120.2 . . ?
C20 C15 C16 118.3(8) . . ?
C20 C15 P1 118.7(6) . . ?
C16 C15 P1 122.7(7) . . ?
C17 C16 C15 120.0(8) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C18 C17 C16 120.3(8) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C19 C18 C17 120.5(9) . . ?
C19 C18 H18 119.7 . . ?
C17 C18 H18 119.7 . . ?
C18 C19 C20 119.1(9) . . ?
C18 C19 H19 120.5 . . ?
C20 C19 H19 120.5 . . ?
C19 C20 C15 121.7(8) . . ?
C19 C20 H20 119.1 . . ?
C15 C20 H20 119.1 . . ?
C15 P1 C1 113.6(4) . . ?
C15 P1 C9 100.8(4) . . ?
C1 P1 C9 103.6(4) . . ?
C15 P1 Pt1 112.0(3) . . ?
C1 P1 Pt1 110.6(3) . . ?
C9 P1 Pt1 115.9(3) . . ?
C26 C21 C22 118.7(7) . . ?
C26 C21 P2 123.3(7) . . ?
C22 C21 P2 118.0(6) . . ?
C23 C22 C21 120.8(7) . . ?
C23 C22 H22 119.6 . . ?
C21 C22 H22 119.6 . . ?
C22 C23 C24 120.8(8) . . ?
C22 C23 H23 119.6 . . ?
C24 C23 H23 119.6 . . ?
C25 C24 C23 118.2(7) . . ?
C25 C24 C27 119.9(8) . . ?
C23 C24 C27 121.8(8) . . ?
C26 C25 C24 121.2(7) . . ?
C26 C25 H25 119.4 . . ?
C24 C25 H25 119.4 . . ?
C21 C26 C25 120.2(8) . . ?
C21 C26 H26 119.9 . . ?
C25 C26 H26 119.9 . . ?
C28 C27 C24 127.1(9) . . ?
C28 C27 H27 116.5 . . ?
C24 C27 H27 116.5 . . ?
C27 C28 H28A 120.0 . . ?
C27 C28 H28B 120.0 . . ?
H28A C28 H28B 120.0 . . ?
C30 C29 C34 118.7(7) . . ?
C30 C29 P2 120.8(6) . . ?
C34 C29 P2 120.6(7) . . ?
C31 C30 C29 120.5(9) . . ?
C31 C30 H30 119.8 . . ?
C29 C30 H30 119.8 . . ?
C32 C31 C30 120.8(10) . . ?
C32 C31 H31 119.6 . . ?
C30 C31 H31 119.6 . . ?
C33 C32 C31 119.7(8) . . ?
C33 C32 H32 120.1 . . ?
C31 C32 H32 120.1 . . ?
C32 C33 C34 119.7(9) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C29 C34 C33 120.5(9) . . ?
C29 C34 H34 119.7 . . ?
C33 C34 H34 119.7 . . ?
C36 C35 C40 119.7(8) . . ?
C36 C35 P2 120.2(6) . . ?
C40 C35 P2 120.0(6) . . ?
C35 C36 C37 119.7(8) . . ?
C35 C36 H36 120.1 . . ?
C37 C36 H36 120.1 . . ?
C38 C37 C36 120.7(8) . . ?
C38 C37 H37 119.6 . . ?
C36 C37 H37 119.6 . . ?
C37 C38 C39 120.5(9) . . ?
C37 C38 H38 119.8 . . ?
C39 C38 H38 119.8 . . ?
C38 C39 C40 119.4(8) . . ?
C38 C39 H39 120.3 . . ?
C40 C39 H39 120.3 . . ?
C35 C40 C39 119.9(8) . . ?
C35 C40 H40 120.1 . . ?
C39 C40 H40 120.1 . . ?
C35 P2 C21 105.7(4) . . ?
C35 P2 C29 102.6(4) . . ?
C21 P2 C29 103.7(4) . . ?
C35 P2 Pt1 116.1(3) . . ?
C21 P2 Pt1 107.7(3) . . ?
C29 P2 Pt1 119.6(2) . . ?
 
_diffrn_measured_fraction_theta_max    0.990
_diffrn_reflns_theta_full              27.48
_diffrn_measured_fraction_theta_full   0.990
_refine_diff_density_max    3.369
_refine_diff_density_min   -1.990
_refine_diff_density_rms    0.207
