data_s92
 
_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 
;
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          'C33 H29 I2 N O3 P2 Pt, C H2 Cl2'
_chemical_formula_sum
 'C34 H31 Cl2 I2 N O3 P2 Pt'
_chemical_formula_weight          1083.33
 
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'I'  'I'  -0.4742   1.8119
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt'  'Pt'  -1.7033   8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_symmetry_cell_setting            Monoclinic
_symmetry_space_group_name_H-M    P2(1)/c
_symmetry_space_group_name_hall   '-P 2ybc'
 
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'
 
_cell_length_a                    16.2353(9)
_cell_length_b                    17.5382(9)
_cell_length_c                    15.1881(6)
_cell_angle_alpha                 90.00
_cell_angle_beta                  108.040(2)
_cell_angle_gamma                 90.00
_cell_volume                      4112.0(4)
_cell_formula_units_Z             4
_cell_measurement_temperature     120(2)
_cell_measurement_reflns_used     75856
_cell_measurement_theta_min       1.02
_cell_measurement_theta_max       27.48
 
_exptl_crystal_description        block
_exptl_crystal_colour             colourless
_exptl_crystal_size_max           0.12
_exptl_crystal_size_mid           0.10
_exptl_crystal_size_min           0.06
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.750
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              2056
_exptl_absorpt_coefficient_mu     5.152
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_correction_T_min   0.5768
_exptl_absorpt_correction_T_max   0.7474
_exptl_absorpt_process_details    'SORTAV (Blessing, 1997)'
 
_exptl_special_details
;
 ?
;
 
_diffrn_ambient_temperature       120(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'Enraf Nonius FR591 rotating anode'
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Enraf Nonius KappaCCD area detector'
_diffrn_measurement_method        'ω and φ scans to fill Ewald sphere'
_diffrn_detector_area_resol_mean  '9.091 pixels/mm'
_diffrn_standards_number          'n/a'
_diffrn_standards_interval_count  'n/a'
_diffrn_standards_interval_time   'n/a'
_diffrn_standards_decay_%         'n/a'
_diffrn_reflns_number             14913
_diffrn_reflns_av_R_equivalents   0.0612
_diffrn_reflns_av_sigmaI/netI     0.1142
_diffrn_reflns_limit_h_min        -20
_diffrn_reflns_limit_h_max        20
_diffrn_reflns_limit_k_min        -21
_diffrn_reflns_limit_k_max        22
_diffrn_reflns_limit_l_min        -19
_diffrn_reflns_limit_l_max        19
_diffrn_reflns_theta_min          1.98
_diffrn_reflns_theta_max          27.41
_reflns_number_total              8442
_reflns_number_gt                 5223
_reflns_threshold_expression      >2sigma(I)
 
_computing_data_collection        
;
'DENZO (Otwinowski and Minor, 1997) & COLLECT (Hooft, 1998) '
;
_computing_cell_refinement        'DENZO and COLLECT'
_computing_data_reduction         'DENZO and COLLECT'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 2008)' 
_computing_molecular_graphics     'PLATON (Watkin, Pearce 1995)'
_computing_publication_material   SHELXL-97
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
 
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[σ²(Fo²)+(0.0989P)²+88.5425P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      SHELXL
_refine_ls_number_reflns          8442
_refine_ls_number_parameters      394
_refine_ls_number_restraints      6
_refine_ls_extinction_coef        0
_refine_ls_R_factor_all           0.1335
_refine_ls_R_factor_gt            0.0752
_refine_ls_wR_factor_ref          0.2220
_refine_ls_wR_factor_gt           0.1921
_refine_ls_goodness_of_fit_ref    1.048
_refine_ls_restrained_S_all       1.048
_refine_ls_shift/su_max           0.037
_refine_ls_shift/su_mean          0.017
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
C1 C 0.5428(6) 0.4147(5) 0.3626(7) 0.025(2) Uani 1 1 d . . .
C34 C 0.792(3) 0.226(3) 0.895(3) 0.25(2) Uiso 1 1 d . . .
H34A H 0.7474 0.2533 0.8459 0.302 Uiso 1 1 calc R . .
H34B H 0.7628 0.1816 0.9119 0.302 Uiso 1 1 calc R . .
C2 C 0.5542(6) 0.3534(6) 0.4258(7) 0.033(3) Uani 1 1 d . . .
H2 H 0.5143 0.3121 0.4140 0.040 Uiso 1 1 calc R . .
C3 C 0.6249(7) 0.3549(6) 0.5050(7) 0.030(3) Uani 1 1 d . . .
H3 H 0.6329 0.3145 0.5486 0.036 Uiso 1 1 calc R . .
C4 C 0.6834(8) 0.4133(6) 0.5221(8) 0.036(3) Uani 1 1 d . . .
H4 H 0.7318 0.4124 0.5767 0.043 Uiso 1 1 calc R . .
C5 C 0.6727(8) 0.4750(6) 0.4597(8) 0.038(3) Uani 1 1 d . . .
H5 H 0.7124 0.5164 0.4726 0.046 Uiso 1 1 calc R . .
C6 C 0.6021(7) 0.4736(6) 0.3782(7) 0.030(3) Uani 1 1 d . . .
H6 H 0.5951 0.5131 0.3338 0.035 Uiso 1 1 calc R . .
C7 C 0.4368(6) 0.4970(6) 0.1969(7) 0.0249(8) Uani 1 1 d U . .
C8 C 0.4249(7) 0.4913(6) 0.1011(7) 0.033(3) Uani 1 1 d . . .
H8 H 0.4227 0.4425 0.0735 0.039 Uiso 1 1 calc R . .
C9 C 0.4166(8) 0.5561(7) 0.0468(8) 0.041(3) Uani 1 1 d . . .
H9 H 0.4094 0.5511 -0.0174 0.049 Uiso 1 1 calc R . .
C10 C 0.4185(8) 0.6280(7) 0.0848(9) 0.047(4) Uani 1 1 d . . .
H10 H 0.4134 0.6722 0.0473 0.056 Uiso 1 1 calc R . .
C11 C 0.4280(7) 0.6347(6) 0.1795(8) 0.035(3) Uani 1 1 d . . .
H11 H 0.4288 0.6834 0.2070 0.042 Uiso 1 1 calc R . .
C12 C 0.4363(7) 0.5683(6) 0.2327(7) 0.034(3) Uani 1 1 d . . .
H12 H 0.4419 0.5731 0.2966 0.041 Uiso 1 1 calc R . .
C13 C 0.3620(6) 0.4275(6) 0.3246(7) 0.026(2) Uani 1 1 d . . .
H13A H 0.3760 0.3952 0.3808 0.031 Uiso 1 1 calc R . .
H13B H 0.3645 0.4814 0.3445 0.031 Uiso 1 1 calc R . .
C14 C 0.2537(7) 0.3290(6) 0.2680(8) 0.037(3) Uani 1 1 d . . .
H14A H 0.1901 0.3232 0.2526 0.044 Uiso 1 1 calc R . .
H14B H 0.2810 0.3078 0.3307 0.044 Uiso 1 1 calc R . .
C15 C 0.2075(7) 0.2920(6) 0.0758(7) 0.029(3) Uani 1 1 d . . .
C16 C 0.2244(8) 0.3211(7) -0.0014(9) 0.043(3) Uani 1 1 d . . .
H16 H 0.2820 0.3350 0.0030 0.052 Uiso 1 1 calc R . .
C17 C 0.1586(10) 0.3307(10) -0.0861(11) 0.065(5) Uani 1 1 d . . .
H17 H 0.1720 0.3493 -0.1388 0.078 Uiso 1 1 calc R . .
C18 C 0.0759(10) 0.3131(11) -0.0918(11) 0.086(6) Uani 1 1 d . . .
H18 H 0.0315 0.3205 -0.1489 0.104 Uiso 1 1 calc R . .
C19 C 0.0534(9) 0.2838(11) -0.0149(12) 0.072(5) Uani 1 1 d . . .
H19 H -0.0048 0.2722 -0.0189 0.087 Uiso 1 1 calc R . .
C20 C 0.1218(8) 0.2730(8) 0.0671(10) 0.057(4) Uani 1 1 d . . .
H20 H 0.1093 0.2518 0.1191 0.069 Uiso 1 1 calc R . .
C21 C 0.2838(6) 0.1803(6) 0.2200(7) 0.024(2) Uani 1 1 d . . .
C22 C 0.3417(8) 0.1601(6) 0.3062(8) 0.038(3) Uani 1 1 d . . .
H22 H 0.3802 0.1971 0.3426 0.046 Uiso 1 1 calc R . .
C23 C 0.3426(8) 0.0844(7) 0.3392(8) 0.047(3) Uani 1 1 d . . .
H23 H 0.3842 0.0689 0.3955 0.056 Uiso 1 1 calc R . .
C24 C 0.2825(8) 0.0346(7) 0.2883(9) 0.048(3) Uani 1 1 d . . .
H24 H 0.2803 -0.0153 0.3120 0.058 Uiso 1 1 calc R . .
C25 C 0.2267(8) 0.0528(6) 0.2071(8) 0.040(3) Uani 1 1 d . . .
H25 H 0.1863 0.0160 0.1733 0.049 Uiso 1 1 calc R . .
C26 C 0.2272(8) 0.1253(7) 0.1711(7) 0.037(3) Uani 1 1 d . . .
H26 H 0.1879 0.1373 0.1120 0.044 Uiso 1 1 calc R . .
C27 C 0.2110(6) 0.4654(6) 0.2709(7) 0.029(3) Uani 1 1 d . . .
C28 C 0.1992(8) 0.5285(7) 0.2160(8) 0.044(3) Uani 1 1 d . . .
H28 H 0.2288 0.5325 0.1712 0.052 Uiso 1 1 calc R . .
C29 C 0.1446(8) 0.5870(7) 0.2245(9) 0.054(3) Uani 1 1 d . . .
H29 H 0.1398 0.6318 0.1881 0.064 Uiso 1 1 calc R . .
C30 C 0.0977(8) 0.5808(8) 0.2846(9) 0.052(3) Uani 1 1 d . . .
H30 H 0.0597 0.6207 0.2893 0.062 Uiso 1 1 calc R . .
C31 C 0.1058(7) 0.5144(7) 0.3401(7) 0.034(3) Uani 1 1 d . . .
C32 C 0.1638(7) 0.4578(6) 0.3344(7) 0.030(3) Uani 1 1 d . . .
C33 C 0.0585(7) 0.5076(7) 0.4089(8) 0.036(3) Uani 1 1 d . . .
N1 N 0.2759(5) 0.4102(5) 0.2666(6) 0.027(2) Uani 1 1 d . . .
O1 O 0.0071(5) 0.5653(5) 0.4104(6) 0.051(2) Uani 1 1 d . . .
O2 O 0.0684(5) 0.4532(4) 0.4614(5) 0.040(2) Uani 1 1 d . . .
H2A H 0.0318 0.4554 0.4902 0.061 Uiso 1 1 calc R . .
O3 O 0.1798(4) 0.3957(4) 0.3892(5) 0.0321(17) Uani 1 1 d . . .
H3A H 0.1583 0.4017 0.4324 0.048 Uiso 1 1 calc R . .
P1 P 0.44355(17) 0.41145(14) 0.26480(17) 0.0245(6) Uani 1 1 d . . .
P2 P 0.29234(17) 0.27657(15) 0.18264(18) 0.0259(6) Uani 1 1 d . . .
I1 I 0.58670(4) 0.32589(4) 0.17227(5) 0.02977(16) Uani 1 1 d . . .
I2 I 0.40605(4) 0.18762(4) 0.06306(5) 0.02925(16) Uani 1 1 d . . .
Pt1 Pt 0.42579(2) 0.30485(2) 0.17806(3) 0.02268(9) Uani 1 1 d . . .
Cl1 Cl 0.8115(16) 0.2746(15) 0.9725(18) 0.417(13) Uiso 1 1 d . . .
Cl2 Cl 0.868(2) 0.1843(18) 0.835(2) 0.531(19) Uiso 1 1 d . . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
C1 C6 1.382(14) . ?
C1 C2 1.415(14) . ?
C1 P1 1.823(10) . ?
C34 Cl1 1.41(5) . ?
C34 Cl2 1.89(5) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C2 C3 1.383(14) . ?
C2 H2 0.9500 . ?
C3 C4 1.366(15) . ?
C3 H3 0.9500 . ?
C4 C5 1.414(16) . ?
C4 H4 0.9500 . ?
C5 C6 1.402(15) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.365(15) . ?
C7 C8 1.410(15) . ?
C7 P1 1.805(10) . ?
C8 C9 1.386(16) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(17) . ?
C9 H9 0.9500 . ?
C10 C11 1.403(17) . ?
C10 H10 0.9500 . ?
C11 C12 1.400(15) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 N1 1.435(12) . ?
C13 P1 1.844(10) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 N1 1.472(13) . ?
C14 P2 1.850(12) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.381(17) . ?
C15 C20 1.398(17) . ?
C15 P2 1.795(10) . ?
C16 C17 1.404(18) . ?
C16 H16 0.9500 . ?
C17 C18 1.35(2) . ?
C17 H17 0.9500 . ?
C18 C19 1.42(2) . ?
C18 H18 0.9500 . ?
C19 C20 1.40(2) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C26 1.380(15) . ?
C21 C22 1.401(15) . ?
C21 P2 1.800(11) . ?
C22 C23 1.418(17) . ?
C22 H22 0.9500 . ?
C23 C24 1.359(18) . ?
C23 H23 0.9500 . ?
C24 C25 1.323(17) . ?
C24 H24 0.9500 . ?
C25 C26 1.385(16) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 C28 1.363(16) . ?
C27 C32 1.412(15) . ?
C27 N1 1.447(13) . ?
C28 C29 1.388(17) . ?
C28 H28 0.9500 . ?
C29 C30 1.362(19) . ?
C29 H29 0.9500 . ?
C30 C31 1.419(17) . ?
C30 H30 0.9500 . ?
C31 C32 1.390(16) . ?
C31 C33 1.481(16) . ?
C32 O3 1.346(12) . ?
C33 O2 1.222(14) . ?
C33 O1 1.318(14) . ?
O2 H2A 0.8400 . ?
O3 H3A 0.8400 . ?
P1 Pt1 2.254(3) . ?
P2 Pt1 2.245(3) . ?
I1 Pt1 2.6667(8) . ?
I2 Pt1 2.6522(7) . ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
C6 C1 C2 121.0(9) . . ?
C6 C1 P1 123.8(7) . . ?
C2 C1 P1 115.2(7) . . ?
Cl1 C34 Cl2 129(3) . . ?
Cl1 C34 H34A 105.0 . . ?
Cl2 C34 H34A 105.0 . . ?
Cl1 C34 H34B 105.0 . . ?
Cl2 C34 H34B 105.0 . . ?
H34A C34 H34B 105.9 . . ?
C3 C2 C1 118.3(9) . . ?
C3 C2 H2 120.9 . . ?
C1 C2 H2 120.8 . . ?
C4 C3 C2 121.4(10) . . ?
C4 C3 H3 119.3 . . ?
C2 C3 H3 119.3 . . ?
C3 C4 C5 120.8(10) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
C6 C5 C4 118.4(10) . . ?
C6 C5 H5 120.8 . . ?
C4 C5 H5 120.8 . . ?
C1 C6 C5 120.0(10) . . ?
C1 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C12 C7 C8 117.4(9) . . ?
C12 C7 P1 122.7(8) . . ?
C8 C7 P1 119.7(8) . . ?
C9 C8 C7 120.9(10) . . ?
C9 C8 H8 119.6 . . ?
C7 C8 H8 119.6 . . ?
C10 C9 C8 120.9(11) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C9 C10 C11 119.1(11) . . ?
C9 C10 H10 120.5 . . ?
C11 C10 H10 120.5 . . ?
C12 C11 C10 118.9(10) . . ?
C12 C11 H11 120.6 . . ?
C10 C11 H11 120.6 . . ?
C7 C12 C11 122.9(10) . . ?
C7 C12 H12 118.6 . . ?
C11 C12 H12 118.6 . . ?
N1 C13 P1 112.1(7) . . ?
N1 C13 H13A 109.2 . . ?
P1 C13 H13A 109.2 . . ?
N1 C13 H13B 109.2 . . ?
P1 C13 H13B 109.2 . . ?
H13A C13 H13B 107.9 . . ?
N1 C14 P2 109.4(7) . . ?
N1 C14 H14A 109.8 . . ?
P2 C14 H14A 109.8 . . ?
N1 C14 H14B 109.8 . . ?
P2 C14 H14B 109.8 . . ?
H14A C14 H14B 108.2 . . ?
C16 C15 C20 117.5(11) . . ?
C16 C15 P2 121.7(9) . . ?
C20 C15 P2 120.8(9) . . ?
C15 C16 C17 121.8(12) . . ?
C15 C16 H16 119.1 . . ?
C17 C16 H16 119.1 . . ?
C18 C17 C16 119.3(15) . . ?
C18 C17 H17 120.4 . . ?
C16 C17 H17 120.4 . . ?
C17 C18 C19 122.0(14) . . ?
C17 C18 H18 119.0 . . ?
C19 C18 H18 119.0 . . ?
C20 C19 C18 116.4(13) . . ?
C20 C19 H19 121.8 . . ?
C18 C19 H19 121.8 . . ?
C15 C20 C19 122.8(14) . . ?
C15 C20 H20 118.6 . . ?
C19 C20 H20 118.6 . . ?
C26 C21 C22 118.0(10) . . ?
C26 C21 P2 126.1(8) . . ?
C22 C21 P2 115.9(8) . . ?
C21 C22 C23 119.8(10) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
C24 C23 C22 118.3(11) . . ?
C24 C23 H23 120.8 . . ?
C22 C23 H23 120.8 . . ?
C25 C24 C23 122.6(12) . . ?
C25 C24 H24 118.7 . . ?
C23 C24 H24 118.7 . . ?
C24 C25 C26 120.2(11) . . ?
C24 C25 H25 119.9 . . ?
C26 C25 H25 119.9 . . ?
C21 C26 C25 120.9(10) . . ?
C21 C26 H26 119.5 . . ?
C25 C26 H26 119.5 . . ?
C28 C27 C32 119.4(10) . . ?
C28 C27 N1 118.8(10) . . ?
C32 C27 N1 121.7(9) . . ?
C27 C28 C29 121.1(12) . . ?
C27 C28 H28 119.4 . . ?
C29 C28 H28 119.4 . . ?
C30 C29 C28 120.5(12) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C29 C30 C31 119.8(11) . . ?
C29 C30 H30 120.1 . . ?
C31 C30 H30 120.1 . . ?
C32 C31 C30 119.3(11) . . ?
C32 C31 C33 119.7(10) . . ?
C30 C31 C33 120.8(11) . . ?
O3 C32 C31 123.0(10) . . ?
O3 C32 C27 117.2(9) . . ?
C31 C32 C27 119.8(10) . . ?
O2 C33 O1 123.0(10) . . ?
O2 C33 C31 122.1(10) . . ?
O1 C33 C31 114.8(10) . . ?
C13 N1 C27 114.6(8) . . ?
C13 N1 C14 113.1(8) . . ?
C27 N1 C14 117.4(8) . . ?
C33 O2 H2A 109.5 . . ?
C32 O3 H3A 109.5 . . ?
C7 P1 C1 108.8(4) . . ?
C7 P1 C13 103.2(5) . . ?
C1 P1 C13 100.5(4) . . ?
C7 P1 Pt1 112.4(3) . . ?
C1 P1 Pt1 115.0(3) . . ?
C13 P1 Pt1 115.7(3) . . ?
C15 P2 C21 108.3(5) . . ?
C15 P2 C14 103.1(5) . . ?
C21 P2 C14 99.8(5) . . ?
C15 P2 Pt1 114.6(4) . . ?
C21 P2 Pt1 112.7(3) . . ?
C14 P2 Pt1 116.9(4) . . ?
P2 Pt1 P1 96.62(10) . . ?
P2 Pt1 I2 85.88(7) . . ?
P1 Pt1 I2 174.62(7) . . ?
P2 Pt1 I1 175.18(7) . . ?
P1 Pt1 I1 87.43(7) . . ?
I2 Pt1 I1 90.31(2) . . ?
 
_diffrn_measured_fraction_theta_max    0.904
_diffrn_reflns_theta_full              27.41
_diffrn_measured_fraction_theta_full   0.904
_refine_diff_density_max    6.180
_refine_diff_density_min   -1.956
_refine_diff_density_rms    0.307
