 
data_s92
 
_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_formula_moiety          'C29 H28 Cl2 N2 P Rh S Se'
_chemical_formula_sum
 'C29 H28 Cl2 N2 P Rh S Se'
_chemical_formula_weight          720.33
 
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S'  'S'   0.1246   0.1234
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Se'  'Se'  -0.0929   2.2259
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Rh'  'Rh'  -1.1178   0.9187
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_symmetry_cell_setting            Monoclinic
_symmetry_space_group_name_H-M    P2(1)/n
_symmetry_space_group_name_hall   '-P 2yn'
 
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x+1/2, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x-1/2, -y-1/2, z-1/2'
 
_cell_length_a                    7.9701(3)
_cell_length_b                    16.3122(8)
_cell_length_c                    21.5858(13)
_cell_angle_alpha                 90.00
_cell_angle_beta                  90.811(2)
_cell_angle_gamma                 90.00
_cell_volume                      2806.1(2)
_cell_formula_units_Z             4
_cell_measurement_temperature     120(2)
_cell_measurement_reflns_used     23546
_cell_measurement_theta_min       2.91
_cell_measurement_theta_max       25.35
 
_exptl_crystal_description        plate
_exptl_crystal_colour             orange
_exptl_crystal_size_max           0.12
_exptl_crystal_size_mid           0.08
_exptl_crystal_size_min           0.01
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.705
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              1440
_exptl_absorpt_coefficient_mu     2.251
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_correction_T_min   0.7740
_exptl_absorpt_correction_T_max   0.9778
_exptl_absorpt_process_details    'SORTAV (Blessing, 1997)'
 
_exptl_special_details
;
 ?
;
 
_diffrn_ambient_temperature       120(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'Enraf Nonius FR591 rotating anode'
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Enraf Nonius KappaCCD area detector'
_diffrn_measurement_method        'ω and φ scans to fill Ewald sphere'
_diffrn_detector_area_resol_mean  '9.091 pixels/mm'
_diffrn_standards_number          'n/a'
_diffrn_standards_interval_count  'n/a'
_diffrn_standards_interval_time   'n/a'
_diffrn_standards_decay_%         'n/a'
_diffrn_reflns_number             24562
_diffrn_reflns_av_R_equivalents   0.1290
_diffrn_reflns_av_sigmaI/netI     0.1103
_diffrn_reflns_limit_h_min        -9
_diffrn_reflns_limit_h_max        9
_diffrn_reflns_limit_k_min        -19
_diffrn_reflns_limit_k_max        19
_diffrn_reflns_limit_l_min        -25
_diffrn_reflns_limit_l_max        25
_diffrn_reflns_theta_min          2.99
_diffrn_reflns_theta_max          25.33
_reflns_number_total              5082
_reflns_number_gt                 3254
_reflns_threshold_expression      >2σ(I)
 
_computing_data_collection        
;
'DENZO (Otwinowski and Minor, 1997) & COLLECT (Hooft, 1998) '
;
_computing_cell_refinement        'DENZO and COLLECT'
_computing_data_reduction         'DENZO and COLLECT'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 2008)' 
_computing_molecular_graphics     'PLATON (Watkin, Pearce 1995)'
_computing_publication_material   SHELXL-97
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
 
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[σ²(Fo²)+(0.0374P)²+1.9448P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          5082
_refine_ls_number_parameters      339
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.1068
_refine_ls_R_factor_gt            0.0529
_refine_ls_wR_factor_ref          0.1076
_refine_ls_wR_factor_gt           0.0927
_refine_ls_goodness_of_fit_ref    0.997
_refine_ls_restrained_S_all       0.997
_refine_ls_shift/su_max           0.000
_refine_ls_shift/su_mean          0.000
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
C1 C 0.6249(8) 0.1268(4) 0.2304(3) 0.0278(15) Uani 1 1 d . . .
C2 C 0.6533(9) 0.1235(4) 0.2995(3) 0.0328(16) Uani 1 1 d . . .
H2A H 0.7496 0.0881 0.3090 0.049 Uiso 1 1 calc R . .
H2B H 0.5531 0.1014 0.3193 0.049 Uiso 1 1 calc R . .
H2C H 0.6756 0.1789 0.3152 0.049 Uiso 1 1 calc R . .
C3 C 0.6871(7) 0.1858(4) 0.1877(3) 0.0252(14) Uani 1 1 d . . .
C4 C 0.7854(8) 0.2608(4) 0.2053(3) 0.0286(15) Uani 1 1 d . . .
H4A H 0.7599 0.2762 0.2480 0.043 Uiso 1 1 calc R . .
H4B H 0.7550 0.3059 0.1773 0.043 Uiso 1 1 calc R . .
H4C H 0.9056 0.2492 0.2020 0.043 Uiso 1 1 calc R . .
C5 C 0.6398(7) 0.1628(3) 0.1260(3) 0.0227(15) Uani 1 1 d . . .
C6 C 0.6937(8) 0.2033(4) 0.0681(3) 0.0326(17) Uani 1 1 d . . .
H6A H 0.6852 0.2629 0.0728 0.049 Uiso 1 1 calc R . .
H6B H 0.6214 0.1854 0.0336 0.049 Uiso 1 1 calc R . .
H6C H 0.8103 0.1884 0.0596 0.049 Uiso 1 1 calc R . .
C7 C 0.5492(8) 0.0864(4) 0.1305(3) 0.0241(14) Uani 1 1 d . . .
C8 C 0.4851(8) 0.0375(4) 0.0760(3) 0.0322(17) Uani 1 1 d . . .
H8A H 0.5750 0.0023 0.0607 0.048 Uiso 1 1 calc R . .
H8B H 0.4481 0.0749 0.0430 0.048 Uiso 1 1 calc R . .
H8C H 0.3904 0.0035 0.0889 0.048 Uiso 1 1 calc R . .
C9 C 0.5398(7) 0.0645(4) 0.1941(3) 0.0243(15) Uani 1 1 d . . .
C10 C 0.4645(9) -0.0119(4) 0.2207(3) 0.0363(17) Uani 1 1 d . . .
H10A H 0.3918 -0.0380 0.1895 0.054 Uiso 1 1 calc R . .
H10B H 0.3982 0.0023 0.2571 0.054 Uiso 1 1 calc R . .
H10C H 0.5543 -0.0499 0.2330 0.054 Uiso 1 1 calc R . .
C11 C 0.4213(7) 0.3480(4) 0.2518(3) 0.0226(14) Uani 1 1 d . . .
C12 C 0.4145(7) 0.3093(4) 0.3091(3) 0.0258(15) Uani 1 1 d . . .
H12 H 0.3881 0.2526 0.3117 0.031 Uiso 1 1 calc R . .
C13 C 0.4461(8) 0.3537(4) 0.3617(3) 0.0264(15) Uani 1 1 d . . .
H13 H 0.4371 0.3282 0.4012 0.032 Uiso 1 1 calc R . .
C14 C 0.4914(8) 0.4357(4) 0.3578(3) 0.0279(16) Uani 1 1 d . . .
C15 C 0.5006(8) 0.4761(4) 0.3022(3) 0.0257(15) Uani 1 1 d . . .
H15 H 0.5306 0.5323 0.3000 0.031 Uiso 1 1 calc R . .
C16 C 0.4640(8) 0.4307(4) 0.2493(3) 0.0246(15) Uani 1 1 d . . .
C17 C 0.4016(7) 0.3647(4) 0.1476(3) 0.0213(14) Uani 1 1 d . . .
C18 C 0.3435(7) 0.2665(4) -0.0198(3) 0.0201(14) Uani 1 1 d . . .
C19 C 0.3046(7) 0.1929(4) -0.0495(3) 0.0246(14) Uani 1 1 d . . .
H19 H 0.2301 0.1552 -0.0306 0.030 Uiso 1 1 calc R . .
C20 C 0.3744(8) 0.1742(4) -0.1067(3) 0.0279(15) Uani 1 1 d . . .
H20 H 0.3467 0.1243 -0.1270 0.034 Uiso 1 1 calc R . .
C21 C 0.4838(8) 0.2288(4) -0.1335(3) 0.0304(16) Uani 1 1 d . . .
H21 H 0.5324 0.2159 -0.1722 0.036 Uiso 1 1 calc R . .
C22 C 0.5231(9) 0.3017(4) -0.1049(3) 0.0334(17) Uani 1 1 d . . .
H22 H 0.5994 0.3386 -0.1237 0.040 Uiso 1 1 calc R . .
C23 C 0.4516(7) 0.3213(4) -0.0489(3) 0.0264(14) Uani 1 1 d . . .
H23 H 0.4762 0.3726 -0.0299 0.032 Uiso 1 1 calc R . .
C24 C 0.0639(8) 0.3500(4) 0.0341(3) 0.0287(16) Uani 1 1 d . . .
C25 C -0.0185(9) 0.3910(4) 0.0809(4) 0.0376(18) Uani 1 1 d . . .
H25 H 0.0215 0.3857 0.1224 0.045 Uiso 1 1 calc R . .
C26 C -0.1573(9) 0.4393(4) 0.0688(5) 0.053(2) Uani 1 1 d . . .
H26 H -0.2149 0.4652 0.1017 0.064 Uiso 1 1 calc R . .
C27 C -0.2115(9) 0.4494(4) 0.0080(5) 0.052(2) Uani 1 1 d . . .
H27 H -0.3045 0.4839 -0.0013 0.063 Uiso 1 1 calc R . .
C28 C -0.1316(10) 0.4102(5) -0.0377(4) 0.050(2) Uani 1 1 d . . .
H28 H -0.1716 0.4163 -0.0791 0.061 Uiso 1 1 calc R . .
C29 C 0.0059(9) 0.3614(4) -0.0264(3) 0.0350(17) Uani 1 1 d . . .
H29 H 0.0613 0.3354 -0.0598 0.042 Uiso 1 1 calc R . .
N1 N 0.3938(6) 0.3100(3) 0.1935(2) 0.0209(11) Uani 1 1 d . . .
N2 N 0.3818(6) 0.3542(3) 0.0867(2) 0.0244(12) Uani 1 1 d . . .
P1 P 0.2524(2) 0.29236(9) 0.05329(8) 0.0218(4) Uani 1 1 d . . .
S1 S 0.4511(2) 0.46493(9) 0.17272(8) 0.0267(4) Uani 1 1 d . . .
Cl1 Cl 0.1990(2) 0.14936(9) 0.25366(7) 0.0284(4) Uani 1 1 d . . .
Cl2 Cl 0.5379(2) 0.49019(11) 0.42608(8) 0.0379(4) Uani 1 1 d . . .
Se2 Se 0.17244(7) 0.18604(4) 0.10455(3) 0.02661(18) Uani 1 1 d . . .
Rh1 Rh 0.41545(6) 0.18105(3) 0.17977(2) 0.01978(14) Uani 1 1 d . . .
 
 
_geom_special_details
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
C1 C3 1.426(9) . ?
C1 C9 1.447(9) . ?
C1 C2 1.507(9) . ?
C1 Rh1 2.171(6) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C5 1.429(8) . ?
C3 C4 1.498(9) . ?
C3 Rh1 2.171(6) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 C7 1.445(9) . ?
C5 C6 1.482(9) . ?
C5 Rh1 2.166(6) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C9 1.422(9) . ?
C7 C8 1.504(9) . ?
C7 Rh1 2.164(6) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.501(9) . ?
C9 Rh1 2.165(6) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.391(8) . ?
C11 C16 1.393(8) . ?
C11 N1 1.416(7) . ?
C12 C13 1.367(8) . ?
C12 H12 0.9500 . ?
C13 C14 1.389(9) . ?
C13 H13 0.9500 . ?
C14 C15 1.373(9) . ?
C14 Cl2 1.756(6) . ?
C15 C16 1.389(9) . ?
C15 H15 0.9500 . ?
C16 S1 1.746(6) . ?
C17 N2 1.334(8) . ?
C17 N1 1.336(7) . ?
C17 S1 1.765(6) . ?
C18 C19 1.393(8) . ?
C18 C23 1.397(8) . ?
C18 P1 1.796(6) . ?
C19 C20 1.395(9) . ?
C19 H19 0.9500 . ?
C20 C21 1.380(9) . ?
C20 H20 0.9500 . ?
C21 C22 1.374(9) . ?
C21 H21 0.9500 . ?
C22 C23 1.383(9) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C24 C25 1.386(9) . ?
C24 C29 1.391(9) . ?
C24 P1 1.815(7) . ?
C25 C26 1.380(10) . ?
C25 H25 0.9500 . ?
C26 C27 1.385(12) . ?
C26 H26 0.9500 . ?
C27 C28 1.344(12) . ?
C27 H27 0.9500 . ?
C28 C29 1.374(10) . ?
C28 H28 0.9500 . ?
C29 H29 0.9500 . ?
N1 Rh1 2.133(5) . ?
N2 P1 1.606(5) . ?
P1 Se2 2.1584(17) . ?
Cl1 Rh1 2.4218(16) . ?
Se2 Rh1 2.5110(8) . ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
C3 C1 C9 106.8(5) . . ?
C3 C1 C2 128.0(6) . . ?
C9 C1 C2 125.0(6) . . ?
C3 C1 Rh1 70.8(3) . . ?
C9 C1 Rh1 70.3(3) . . ?
C2 C1 Rh1 128.1(5) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 C5 109.6(6) . . ?
C1 C3 C4 124.9(5) . . ?
C5 C3 C4 125.5(6) . . ?
C1 C3 Rh1 70.8(3) . . ?
C5 C3 Rh1 70.6(3) . . ?
C4 C3 Rh1 124.5(4) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 C7 106.8(5) . . ?
C3 C5 C6 126.3(6) . . ?
C7 C5 C6 126.3(6) . . ?
C3 C5 Rh1 70.9(3) . . ?
C7 C5 Rh1 70.4(4) . . ?
C6 C5 Rh1 130.0(4) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C9 C7 C5 108.4(5) . . ?
C9 C7 C8 126.8(6) . . ?
C5 C7 C8 124.7(6) . . ?
C9 C7 Rh1 70.8(3) . . ?
C5 C7 Rh1 70.6(3) . . ?
C8 C7 Rh1 126.8(4) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 C1 108.4(5) . . ?
C7 C9 C10 127.2(6) . . ?
C1 C9 C10 124.3(6) . . ?
C7 C9 Rh1 70.8(3) . . ?
C1 C9 Rh1 70.7(3) . . ?
C10 C9 Rh1 126.8(4) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 C16 119.2(6) . . ?
C12 C11 N1 125.8(5) . . ?
C16 C11 N1 115.0(5) . . ?
C13 C12 C11 119.3(6) . . ?
C13 C12 H12 120.3 . . ?
C11 C12 H12 120.3 . . ?
C12 C13 C14 120.3(6) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C15 C14 C13 122.2(6) . . ?
C15 C14 Cl2 118.5(5) . . ?
C13 C14 Cl2 119.3(5) . . ?
C14 C15 C16 116.8(6) . . ?
C14 C15 H15 121.6 . . ?
C16 C15 H15 121.6 . . ?
C15 C16 C11 122.2(6) . . ?
C15 C16 S1 128.1(5) . . ?
C11 C16 S1 109.6(5) . . ?
N2 C17 N1 129.8(5) . . ?
N2 C17 S1 116.4(4) . . ?
N1 C17 S1 113.8(4) . . ?
C19 C18 C23 118.6(6) . . ?
C19 C18 P1 121.1(5) . . ?
C23 C18 P1 120.2(4) . . ?
C20 C19 C18 120.5(6) . . ?
C20 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
C21 C20 C19 119.5(6) . . ?
C21 C20 H20 120.2 . . ?
C19 C20 H20 120.2 . . ?
C22 C21 C20 120.8(6) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C21 C22 C23 119.9(6) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
C22 C23 C18 120.7(6) . . ?
C22 C23 H23 119.7 . . ?
C18 C23 H23 119.7 . . ?
C25 C24 C29 117.8(6) . . ?
C25 C24 P1 118.9(5) . . ?
C29 C24 P1 123.1(5) . . ?
C26 C25 C24 121.6(8) . . ?
C26 C25 H25 119.2 . . ?
C24 C25 H25 119.2 . . ?
C25 C26 C27 119.1(8) . . ?
C25 C26 H26 120.4 . . ?
C27 C26 H26 120.4 . . ?
C28 C27 C26 119.6(7) . . ?
C28 C27 H27 120.2 . . ?
C26 C27 H27 120.2 . . ?
C27 C28 C29 122.1(8) . . ?
C27 C28 H28 119.0 . . ?
C29 C28 H28 119.0 . . ?
C28 C29 C24 119.8(8) . . ?
C28 C29 H29 120.1 . . ?
C24 C29 H29 120.1 . . ?
C17 N1 C11 111.0(5) . . ?
C17 N1 Rh1 123.4(4) . . ?
C11 N1 Rh1 122.9(4) . . ?
C17 N2 P1 126.1(4) . . ?
N2 P1 C18 106.0(3) . . ?
N2 P1 C24 107.5(3) . . ?
C18 P1 C24 105.4(3) . . ?
N2 P1 Se2 117.9(2) . . ?
C18 P1 Se2 112.8(2) . . ?
C24 P1 Se2 106.5(2) . . ?
C16 S1 C17 90.2(3) . . ?
P1 Se2 Rh1 97.29(5) . . ?
N1 Rh1 C7 144.5(2) . . ?
N1 Rh1 C9 152.2(2) . . ?
C7 Rh1 C9 38.4(2) . . ?
N1 Rh1 C5 106.2(2) . . ?
C7 Rh1 C5 39.0(2) . . ?
C9 Rh1 C5 64.9(2) . . ?
N1 Rh1 C3 92.1(2) . . ?
C7 Rh1 C3 64.3(2) . . ?
C9 Rh1 C3 64.3(2) . . ?
C5 Rh1 C3 38.5(2) . . ?
N1 Rh1 C1 113.3(2) . . ?
C7 Rh1 C1 64.9(2) . . ?
C9 Rh1 C1 39.0(2) . . ?
C5 Rh1 C1 65.1(2) . . ?
C3 Rh1 C1 38.4(2) . . ?
N1 Rh1 Cl1 93.38(13) . . ?
C7 Rh1 Cl1 122.13(17) . . ?
C9 Rh1 Cl1 92.72(17) . . ?
C5 Rh1 Cl1 157.64(16) . . ?
C3 Rh1 Cl1 132.44(16) . . ?
C1 Rh1 Cl1 97.56(17) . . ?
N1 Rh1 Se2 89.71(13) . . ?
C7 Rh1 Se2 94.94(17) . . ?
C9 Rh1 Se2 117.93(17) . . ?
C5 Rh1 Se2 107.01(16) . . ?
C3 Rh1 Se2 143.99(16) . . ?
C1 Rh1 Se2 156.84(17) . . ?
Cl1 Rh1 Se2 83.26(4) . . ?
 
_diffrn_measured_fraction_theta_max    0.992
_diffrn_reflns_theta_full              25.33
_diffrn_measured_fraction_theta_full   0.992
_refine_diff_density_max    0.554
_refine_diff_density_min   -0.687
_refine_diff_density_rms    0.126
